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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Titanium(III) phosphide ： ウィキペディア英語版 Titanium(III) phosphide Titanium(III) phosphide (TiP) is an inorganic chemical compound of titanium and phosphorus. Normally encountered as a grey powder,〔 it is a metallic conductor with a high melting point.〔H.G. Von Schnering, W. Hönle ''Phosphides - Solid state chemistry'' Encyclopedia of Inorganic Chemistry Ed. R. Bruce King (1994) John Wiley & Sons ISBN 0-471-93620-0〕 It is not attacked by common acids or water.〔 Its physical properties stand in contrast to the group 1 and group 2 phosphides that contain the P3− anion (such as Na3P), which are not metallic and are readily hydrolysed.〔 Titanium phosphide is classified as a "metal-rich phosphide", where extra valence electrons from the metal are delocalised.〔 Titanium phosphide can be prepared by the reaction of TiCl4 and PH3.〔 There are other titanium phosphide phases, including Ti3P,〔Hydrogen absorption in Ti3P Halter U., Mrowietz M., Weiss A Journal of the less-common metals 1986 118 343-348〕 Ti2P,〔Structure of Ti2P solved by three-dimensional electron diffraction data collected with the precession technique and high-resolution electron microscopy M. Gemmi, X. D. Zou, S. Hovmöller, A. Migliori, M. Vennström and Y. Andersson Acta Cryst. (2003). A59, 117-126 PMID 12604849〕 Ti7P4,〔New Phases in the Ti-P and Ti-Cu-P Systems, Carrillo C W., Lundström T Acta Chem.Scand., Series A: (1979), 33, 401-402〕 Ti5P3,〔Crystal Structure Refinement of Ti5P3 Carrillo C W., Lundström T Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry 1980 34 415-419〕 and Ti4P3.〔Phase Relationships in the Ti-P System with some Notes on the Crystal Structures of TiP2 and ZrP2, Snell P.O, Acta Chem. Scand. 1968 22 1942-1952〕 Titanium phosphide should not be confused with titanium phosphate or titanium isopropoxide, both of which are sometimes known by the acronym TIP. ==References== 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Titanium(III) phosphide」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.